| Crystal Research and Technology |
By marking the solid-liquid interfaces during a stepwise decrease of the height of a stationary molten zone of Bi0.5Sb1.5Te3 reasonable and changing curvatures of the interfaces are determined. In opposite to the lower interface the upper interface changes its shape from convex to concave for aspect ratios ar >= 2. The differences regarding the shape of both interfaces are indirectly due to the different flow intensities in both half zones. Furthermore, in addition to experiments described in Part 1 of this paper the molten zone was moved dynamically through the sample (zone melting). By estimating solutal and thermal RAYLEIGH numbers the solutal contribution to buoyancy convection is considered as negligible compared to the thermal part for the investigated zone heights. Time-dependent convection during zone melting results in pronounced striations. With suitable models for the correlation between the oscillations of temperature, growth rate and microscopical concentration it was possible to estimate the shape and quantity of oscillating compositional inhomogeneities (striations).
Keywords: interface shape, striations, flow phenomena, measurement