Crystal Research and Technology
Cryst. Res. Technol. 36 (2001) 339 - Abstract -

E. Rakovský, L. Zúrková, J. Marek*

Department of Inorganic Chemistry, Comenius University Bratislava, Slovak Republic
*Laboratory of Biomolecular Structure and Dynamics and Department of Inorganic Chemistry, Masaryk University Brno, Czech Republic

1,6-Hexanediammonium Dihydrogendecavanadate Dihydrate, (H3N—(CH2)6—NH3)2H2V10O28 · 2 H2O

The crystal structure of (H3N—(CH2)6—NH3)2H2V10O28 · 2 H2O consists of dihydrogendecavanadate anion with Ci symmetry, two 1,6-hexanediammonium cations and two water molecules. The structure has a P-1 space group symmetry with one of the cations in special position; this cation is disordered. The polyanion of most usual protonation type is similar as formed in other known dihydrogendecavanadates.

Keywords: dihydrogendecavanadate, dihydrate, X-ray diffraction, structure analysis, disordered cation, bond-length/bond-number calculation


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