Crystal Research and Technology
Cryst. Res. Technol. 36 (2001) 403 - Abstract -

B. Iliescu, I. Enculescu, I. Pera, G. Alexe, S. Polosan, A. Stanculescu

National Institute of Materials Physic, Bucharest, Romania

Chemical Composition of Structures Obtained Inside Quartz Crystals by Sodium Electrodiffusion

Dendritic structures were grown inside quartz crystals by electrodiffusion of sodium ions from a NaCl layer at the anode. An experimental arrangement using a point cathode and a graphite plate anode was employed. X-ray diffraction experiments were carried out, the structures chemical composition was found to be a mixture of sodium silicates. The chemical composition evolution in time was observed. There were made VIS and UV optical absorption spectroscopy measurements of these structures, a colloidal band being found. Thermoluminescence glow curves were measured. Based on the experimental results and observations a growth model is proposed.

Keywords: sweeping, quartz, metal electrodiffusion, ionic conductivity, silicates



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