Crystal Research and Technology
Cryst. Res. Technol. 37 (2002) 169 - Abstract -

K. Yanxiong, L. Jianmin*, Z. Yugen, H. Gaofei, J. Zheng, L. Zhibin

Department of Chemistry, University of Science and Technology of China
*Department of Chemical Physics, University of Science and Technology of China

Solvothermal Synthesis and Characterization of an One-Dimensional Zinc Phosphate

An one dimensional zinc phosphate, [(enH2)2][Zn(PO4)2] (I), has been synthesized at 433 K under solvothermal conditions. The structures of this compound was determined using single crystal X-ray diffraction. Compound (I) contains one-dimensional chains of formula [Zn(PO4)2] constructed from corner-sharing 4-membered rings of alternating ZnO4 and PO4 tetrahedra. The one-dimensional chains are surrounded by dipronated ethylenediamionium through hydrogen bonds.

Keywords: one-dimensional, phosphate, solvothermal, structure, X-ray diffraction, zinc


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