C. Arici, D. Ülkü, O. Atakol, M. Aksu: Crystal Structure Analysis of {[µ-N,N'-Bis(salicylidene)-2,2’-dimethyl-1,3-propanediaminato](dimethylformamide) zinc(II)}diiodomercury(II)

Crystal Research and Technology

Cryst. Res. Technol. 37 (2002) 520 - Abstract -

C. Arici, D. Ülkü, O. Atakol*, M. Aksu**

Department of Engineering Physics, University of Hacettepe, Beytepe-Ankara, 06532, Turkey
*Department of Chemistry, University of Ankara, Ankara, 06100, Turkey
**Department of Chemistry, University of Erciyes, Yozgat Faculty of Science, Yozgat, 66100, Turkey

Crystal Structure Analysis of {[µ-N,N'-Bis(salicylidene)-2,2’-dimethyl-1,3-propanediaminato](dimethylformamide) zinc(II)}diiodomercury(II)

The title compound, a hetero-dinuclear complex with Zn^II and Hg^II ions, forms crystals which belong to the monoclinic system, space group P2₁/n, with unit cell dimensions a=11.2217(12), b=17.7493(11), c=13.9293(13) Å, β=94.830(3)° , V=2764.5(4) Å³. The cell contains four molecules. The Zn…Hg distance is 3.5362(15) Å.

Keywords: crystal structure, dinuclear complex

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