Synthesis, Structure and Characterizations of a Molybdenum Sulfide Complex with inorganic Cluster [Mo3S13]2- and Organic Amine Me4N+ by S. Lu, Y. Ke, J. Li, Y. Zhang

Crystal Research and Technology

Cryst. Res. Technol. 37 (2002) 1153 - Abstract -

S. Lu, Y. Ke, J. Li, Y. Zhang*

Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China
*Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China

Synthesis, Structure and Characterizations of a Molybdenum Sulfide Complex with inorganic Cluster [Mo₃S₁₃]^2- and Organic Amine Me₄N⁺

The complex of (Me₄N)₂Mo₃S₁₃ (I) has been synthesized under mild hydrothermal condition. The crystal structure was determined by single crystal X-ray diffraction at room temperature. Crystal data: M = 854.91, Trigonal, space group P3 (No. 143), a = 11.2351(8) Å, c = 5.8885(6) Å, and Z = 1, There is an inorganic [Mo₃S₁₃]^2- core composed of a Mo₃-triangle, a μ₃-S atom, three doubly bridging disulfide and three terminal disulfide. Two organic amine ions act as the positive charge to balance the [Mo₃S₁₃]^2- cluster.

Keywords: hydrothermal, crystal, structure, X-ray, molybdenum, disulfide

The full text of this paper in pdf-Format:

If you came directly to this page, click this symbol

to go to the homepage of CRT.