Structure and electrochemical behaviour of Bis[N-(4-methylphenyl)salicylaldimine]copper(II) N,N'dimethylformamide solvate by L. Tatar Yildirim, K. C. Emregul, R. Kurtaran, O. Atakol

Crystal Research and Technology

Cryst. Res. Technol. 37 (2002) 1344 - Abstract -

L. Tatar Yildirim, K. C. Emregul*, R. Kurtaran**, O. Atakol*

Department of Engineering Physics, University of Hacettepe, Ankara, Turkey
*Department of Chemistry, University of Ankara, Ankara, Turkey
**Department of Chemistry, Faculity of Arts and Science, University of Balikesir, Balikesir, Turkey

Structure and electrochemical behaviour of Bis[N-(4-methylphenyl)salicylaldimine]copper(II) N,N'dimethylformamide solvate

The molecular model of mononuclear complex formed, through a reaction between N-(4-methylphenyl)salicylaldimine and Cu^II ion was determined using x-ray diffraction method. The Cu^II coordination was found to have a distorted square-planar structure and a cis coordination geometry was observed within the surrounding of the copper. The electro chemical behaviour of the mononuclear copper complex was studied with cyclic voltammetry.

Keywords: crystal structure, mononuclear Cu complex, Schiff base, element analysis, thermal analysis, IR, cyclic voltammetry

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