Crystal Research and Technology
Cryst. Res. Technol. 38, 113 (2003) - Abstract -

Effect of Mn(II) ions on the growth of ammonium oxalate monohydrate crystals from aqueous solutions:
II. Growth kinetics


K. Sangwal and E. Mielniczek-Brzóska*

Department of Applied Physics, Institute of Physics, Technical University of Lublin, ul. Nadbystrzycka 38, 20-618 Lublin, Poland
*Institute of Chemistry and Environmental Protection, Pedagogical University of Czestochowa, ul. Armii Krajowej 13/15, 42-200 Czestochowa, Poland

Keywords    adsorption isotherm; growth models, impurities; surface processes, growth from solutions, ammonium oxalate monohydrate

The experimental results of the effect of concentration of Mn(II) ions on the growth kinetics of different faces of ammonium oxalate monohydrate single crystals from aqueous solutions at a constant temperature and different predefined supersaturations are described and discussed. It was observed that: (1) at a given supersaturation σ, Mn(II) ions lead to a decrease in the growth rates of different faces of AO crystals, (2) the growth of a particular face of the crystals occurs above a critical supersaturation σd but there is also another supersaturation barrier σ* when the rate abruptly increases with σ, (3) the values of σd and σ* increase with increasing concentration of the impurity, and (4) the values of σd depend on the growth kinetics of a face but those of σ* are independent of face growth kinetics. The experimental R(σ) data for different Mn(II) concentrations ci were analysed according to the model involving complex source of cooperating screw dislocations and concepts of instantaneous and time-dependent impurity adsorption. It was found that: (1) for a given face the differential heat of adsorption Qdiff is higher during instantaneous impurity adsorption than that during time-dependent adsorption, and (2) the values of Qdiff involved during instantaneous adsorption are related with face growth kinetics but those during time-dependent adsorption are independent of face growth kinetics.




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