Crystal Research and Technology
Cryst. Res. Technol. 38, 755 (2003) - Abstract -

Formation of a new F.C.C. τ2 phase in rapidly quenched Al55Cu35V10 alloy

D. K. Misra, R. S. Tiwari, and O. N. Srivastava

Department of Physics, Banaras Hindu University, Varanasi 221005, India

Keywords microstructure, quasicrystals, vacancy ordered phase, crystalline approximant, rapid quenching
PACS 61.46.+W, 61.10-I, 61.14-X, 61.43.-J
DOI 10.1002/crat.200310091

X-ray diffraction and transmission electron microscopy experiments were carried out to study the structure of rapidly solidified as-cast and annealed Al55Cu35V10 alloy. The as-cast Al55Cu35V10 alloy shows the presence of a new f.c.c. τ2 phase (a=0.58nm) along with a b.c.c. (a=0.89nm) phase which after subsequent annealing transforms into single f.c.c. phase (a=0.58nm). In this paper, it is also reported that these phases are crystalline approximants to an icosahedral phase on the basis of e/a (valence electron per atom) constant line.




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