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Crystal Research and Technology |
Cryst. Res. Technol. 39,
89 (2004) - Abstract -
Synthesis and structure of 2D- and 3D- inorganic-organic coordination olymers: based on Ag-hmt subunit
Sheming Lu, Shoubo Qin, Yanxiong Ke, Jianmin Li, Hongxia Pei, Shuxi Zhou, Xintao Wu*, Wenxin Du*
Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China
*State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure Matter, Chinese Academy of Science, Fuzhou, 350002, P. R. China
| Keywords | silver, hexamethylenetetramine, crystal structure, coordination polymer, X-ray crystallography, three-dimension |
| PACS | 61.66.Hq |
| DOI | 10.1002/crat.200310154 |
Two new inorganic-organic complexes, namely, [Ag2(hmt)2]Cr2O7.H2O (1) and [Ag(hmt)(tar)0.5].H2O (2), (hmt = hexamethylenetetramine, Tar = tartarate,), have been synthesized in H2O/CH3CN solvent at room temperature. Both molecules have the common [Ag3hmt3]3+ layers. Compound 1 is a two-dimensional structure, and Complex 2 shows three-dimensional topology. In complex 2, the tartarate molecules are connected with adjacent layers to form parallelogram pores of 18.55x7.44 Å, which are occupied by two water molecules.
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