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Crystal Research and Technology |
Cryst. Res. Technol. 39,
540 (2004) - Abstract -
Impurity adsorption mechanism of borax for a suspension growth condition: A comparison of models and experimental data
Sattar Al-Jibbouri and Joachim Ulrich
Martin-Luther-Universität Halle-Wittenberg, FB IW/ TVT, D-06099 Halle (Saale), Germany
| Keywords | impurity, adsorption isotherms, crystal growth rate, impurity effectiveness factor |
| PACS | 81.10.-h |
| DOI | 10.1002/crat.200310222 |
A fluidized bed crystallizer is employed to investigate the growth and dissolution rates of MgSO4.7H2O from aqueous solutions in the presence of borax as impurity at 25°C. By adding 0.5, 1, 2 and 5 wt % of impurity the pH value changes from 6.7 to 7.11, while the saturation temperature shifts to 24.8, 24.4, 24 and 23.1°C, respectively. The data on crystal growth rates from aqueous solutions as a function of impurity concentration are discussed from the standpoint of Cabrera and Vermileya, and Kubota and Mullin. The value of the impurity effect, α θ eq, determined from analysis of the data on growth kinetics was found to be in good agreement with the value obtained from direct adsorption experiments. The estimated value of the average spacing between the adjacent adsorption active sites and the average distance between the neighbouring impurity-adsorbed sites are also reported.
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