Crystal structure analysis of {[μ-N,N'-Bis(salicylidene)-1,3-propanediaminato]nickel(II)}dichloromercury(II) by C. Arici, D. Ülkü, O. Atakol, and M. N. Tahir

Crystal Research and Technology

Cryst. Res. Technol. 41, 204 (2006) - Abstract -

Crystal structure analysis of {[μ-N,N'-Bis(salicylidene)-1,3-propanediaminato]nickel(II)}dichloromercury(II)

C. Arici, D. Ülkü, O. Atakol*, and M. N. Tahir**

Department of Engineering Physics, University of Hacettepe, Beytepe, Ankara, 06800, Turkey
*Department of Chemistry, University of Ankara, Tandođan, Ankara, 06100, Turkey
**University of Sargodha, Department of Physics, Sargodha, Punjab, Pakistan

Keywords	crystal structure, dinuclear complex, nickel and mercury complex
PACS	61.66.Hq
DOI	10.1002/crat.200510556

The title compound, a hetero-dinuclear complex with Ni(II) and Hg(II) ions, forms crystals which belong to the triclinic system, space group P-1, with unit cell dimensions a=8.9620(12), b=9.2370(11), c=12.0810(13) Å, α=92.100(3)° , β=105.317(5)°, γ=110.502(3)°, V=894.2(2) Å³. The cell contains two molecules. The Ni…Hg distance is 3.4859(7) Å. The distance Hg...Hg^a (symmetry code: -x,-y,-z) between the neighbouring molecules is 4.7514(7) Å.

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