Crystal Research and Technology
Cryst. Res. Technol. 41, 225 (2006) - Abstract -

Growth of benzophenone single crystals from solution: A novel approach with 100% solute - crystal conversion efficiency

K. Sankaranarayanan and P. Ramasamy*

Crystal Research Centre, Alagappa University, Karaikudi-630 003, India
*Crystal Growth Centre, Anna University, Chennai-600025, India

Keywords solvents, growth from solution, single crystal growth, organic compounds, nonlinear optic materials
PACS 61.10.Nz, 42.70.N
DOI 10.1002/crat.200510564

An unidirectional 60mm diameter benzophenone single crystal was successfully grown by utilizing a novel crystal growth method at room temperature. <110> oriented single crystal ingots were grown out of xylene as solvent and by fixing a seed at the bottom of the ampoule. The obtained benzophenone ingots with the sizes of 10mm, 25mm and 60mm diameter evident that ease in increasing the diameter of the ingot. The orientation of the ingot and the crystalline quality were justified by X-ray studies. TG and DTA evaluated the thermal properties of the grown crystal. The optical transmission study and the powder SHG measurement show the suitability of the ingot for nonlinear optical applications. The achieved solute-crystal conversion efficiency of hundred percent shows vital advantage of this technique for cost effectiveness. The microbial growth as in the case of amino acid based growth solutions can be more effectively controlled in the present method since the freshly prepared growth solution can be constantly made available to the growing crystal.





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