Refinement, comparisonal study and EPR measurements on the molecular structure of NN-diethyldithiocarbamate of Zn(II) and Cd(II) by S. Pokhrel and K. S. Nagaraja

Crystal Research and Technology

Cryst. Res. Technol. 41, 1246 (2006) - Abstract -

Refinement, comparisonal study and EPR measurements on the molecular structure of NN-diethyldithiocarbamate of Zn(II) and Cd(II)

S. Pokhrel and K. S. Nagaraja

Department of Chemistry, Loyola Institute of Frontier Energy(LIFE), Loyola College, Chennai 600 034, India

Keywords	zinc dithiocarbamate, cadmium dithiocarbamates, EPR
PACS	33.35.+r, 61.50.Lt, 61.66.Fn
DOI	10.1002/crat.200610758

The accidental formation of Zn(II) bis(N,N-diethyldithiocarbamate) (1) and Cd(II) bis(N,N diethyldithiocarbamate) (2) during the synthesis of the target heterobinuclear Mo-Cd-dithiocarbamate or Mo-Zn-dithiocarbamtes were crystallized and the molecular structures were determined. As the dispute over the presence of Mo with Zn-dithiocarbamate existed, single crystal EPR measurement was performed. Both the molecular structures 1 and 2 were identical dimers. The cell parameters of the crystals were refined with low residual factor compared to those of the reported structures.

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