Preparation, single crystal growth and characterization of bis(tetrabutylammonium)bis(4,5-dithiolato-1,3-dithiole-2-thione)copper by X. Q. Wang, D. Xu, Q. Ren, G. H. Zhang, X. B. Sun, X. Q. Hou, W. F. Guo, and H. Lü

Crystal Research and Technology

Cryst. Res. Technol. 42, 349 (2007) - Abstract -

Preparation, single crystal growth and characterization of bis(tetrabutylammonium)bis(4,5-dithiolato-1,3-dithiole-2-thione)copper

X. Q. Wang, D. Xu, Q. Ren*, G. H. Zhang, X. B. Sun*, X. Q. Hou, W. F. Guo, and H. Lü**

State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, P. R. China
*Department of Optics, Shandong University, Jinan 250100, P. R. China
**Shandong Shanda Omrsoft Limited Company, Jinan 250100, P. R. China

Keywords	crystal growth, spectroscopic characterizations, X-ray diffraction, thermal properties
PACS	81.10.-h, 61.10.Nz, 78.30.-j, 71.35.Cc, 81.70.Pg
DOI	10.1002/crat.200610827

The preparation and single crystal growth of bis(tetrabutylammonium)bis(4,5-dithiolato-1,3-dithiole- 2-thione)copper, (I), are described. The energy gap of (I) is about 2.38 eV. The nonlinear optical susceptibility is about 1.3x10^-3 esu at 1064 nm. The characterization of (I) has been performed by electronic absorption, infrared and X-ray powder diffraction spectroscopy. The thermal behavior of (I) has been investigated by means of thermogravimetric analysis (TGA) and differential thermal analysis (DTA) measurements in air.

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