Crystal Research and Technology
Cryst. Res. Technol. 42, 613 (2007) - Abstract -

Estimation of spontaneous antipolarization of ADP based on magnitude of fourth-order electrooptic effect

P. Górski, R. Ledzion, and W. Kucharczyk

Institute of Physics, Technical University of £ódŸ, ul. Wólczańska 219, 93-005 Lódz, Poland

Keywords fourth-order electrooptic effect, quadratic electrooptic effect, NH4H2PO4, spontaneous antipolarization
PACS 78.20.Jq, 77.84.Fa
DOI 10.1002/crat.200610872

Applying the relationship between the spontaneous birefringence of ADP appearing in the low-temperature antiferroelectric phase with the spontaneous antipolarization, and taking into consideration the known experimental values for the quadratic and fourth-order electrooptic effects, an estimate is made of the lower limit of the spontaneous antipolarization. The estimation, which employs the fourth-order electrooptic effect, gives the antipolarization P = 1.2.10-2 Cm-2, a value comparable in magnitude to the spontaneous polarization observed in ferroelectrics belonging to the KDP family of crystals.





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