Crystal Research and Technology
Cryst. Res. Technol. 42, 914 (2007) - Abstract -

Incorporation of surface tension to interface energy balance in crystal growth

M. Yildiz and S. Dost

Crystal Growth Laboratory, Department of Mechanical Engineering, University of Victoria, Victoria, BC, V8W 3P6, Canada

Keywords crystal growth from solution, jump conditions, Gibbs-Thomson effect
PACS 81.10.Dn, 47.10.ab, 47.55.dm
DOI 10.1002/crat.200710927

Effect of surface tension across a growth interface is known as the Gibbs-Thomson effect, and the associated energy balance is widely referred to as the Stefan condition in the literature, which is derived from thermodynamics. In this article, the interface energy balance that accounts for the effect of surface tension is derived by writing the jump condition for the energy balance on a surface of discontinuity which represents in crystal growth the evolving growth interface (solidification front) between the liquid and solid phases. To the best of our knowledge, the derivation of energy balance by writing jump conditions on a surface of discontinuity (interface) is new.





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