Mixed crystal of bis(μ2-N,N-di-n-butyldithiocarbamato-S,S,S’)-bis(N,N-di-n-butyldithiocarbamato-S,S’)-di-zinc(II) and bis(μ2-N,N-di-n-butyldithiopercarbamato-S,O,O’)-bis(N,N-di-n-butyldithiocarbamato-S,S’)-di-zinc(II) by F. Emmerling, R. Becker, and G. Reck

Crystal Research and Technology

Cryst. Res. Technol. 42, 1018 (2007) - Abstract -

Mixed crystal of bis(μ2-N,N-di-n-butyldithiocarbamato-S,S,S’)-bis(N,N-di-n-butyldithiocarbamato-S,S’)-di-zinc(II) and bis(μ2-N,N-di-n-butyldithiopercarbamato-S,O,O’)-bis(N,N-di-n-butyldithiocarbamato-S,S’)-di-zinc(II)

F. Emmerling, R. Becker, and G. Reck

Department of Analytical Chemistry, Bundesanstalt für Materialforschung und –prüfung (BAM), Richard-Willstätter-Straße 11, 12489 Berlin, Germany

Keywords	crystal structure, zinc, dithiocarbamate, dithiopercarbamate
PACS	61.66.Hq
DOI	10.1002/crat.200710956

The title compounds Zn₂[S₂CN(n-C₄H₉)₂]₄ 1 and Zn₂[(S(SO)CN(n-C₄H₉)₂)(S₂CN(n-C₄H₉)₂)]₂ 3 build mixed crystals in the ratio 0.42 : 0.58. Each compound forms dimers, in which the monomer moieties are related via a two-fold axis, coinciding with that of the monoclinic space group C2/c. The lattice parameters are a = 23.581(9), b = 17.112(5), c = 16.372(9) Å, and β = 128.33(3)o.

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