Hydrothermal synthesis and crystal structure of a three-dimensional polyoxovanadate by Huiyuan Ma, Xiaodan Wang, Baoxia Dong, Chunxiang Li, and Lizhou Wu

Crystal Research and Technology

Cryst. Res. Technol. 43, 28 (2008) - Abstract -

Hydrothermal synthesis and crystal structure of a three-dimensional polyoxovanadate

Huiyuan Ma, Xiaodan Wang, Baoxia Dong*, Chunxiang Li, and Lizhou Wu

Chemistry Department of Harbin Normal University, Harbin 150025, China
*Faculty of Chemistry, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun, Jilin, 130024, China

Keywords	hydrothermal synthesis, crystal structure, vanadium oxide, isopolyanions
PACS	61.66.Fn
DOI	10.1002/crat.200710986

A three-dimensional polyoxovanadate formulated as HV₃O₈·H₂O has been synthesized by hydrothermal method. Its structure was established by single-crystal X-ray diffraction. The crystal belong to monoclinic system with a space group P2₁/m, a= 4.9980 (10) Å, b=8.4188 (17) Å, c = 7.8614 (16) Å, α = 90.00°, β =96.40 (3)°, γ =90.00°, V= 328.72(11) Å³.

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